Thiazyltrifluorid-Komplexe von Mg und Zn / Thiazyltrifluoride Complexes of Mg and Zn

Abstract

Translation of the Bible or any other text unavoidably involves a determination about its meaning. There have been different views of meaning from ancient times up to the present, and a particularly Enlightenment and Modernist view is that the meaning of a text amounts to whatever the original author of the text intended it to be. This article analyzes the authorial-intent view of meaning in comparison with other models of literary and legal interpretation. Texts are anchors to interpretation but are subject to individualized interpretations. It is texts that are translated, not intentions. The challenge to the translator is to negotiate the meaning of a text and try to choose the most salient and appropriate interpretation as a basis for bringing the text to a new audience through translation.

Thiazyl Trifluoride (NSF3) Adducts and Imidodifluorosulfate (F2OSN-) Derivatives of Hg(OTeF5)2

“…The S–F (1.489(6)–1.516(7) Å) bond lengths are comparable to those of [M­(NSF 3 ) 4 ]­[AsF 6 ] 2 (Mn, 1.501(5)–1.511(4) Å; Zn, 1.423(9)–1.515(5) Å), , [Re­(CO) 5 NSF 3 ]­[AsF 6 ] (1.499(10) Å), and [CpFe­(CO) 2 ­NSF 3 ]­[AsF 6 ] (1.512(3)–1.519(3) Å) . The shorter S–F bond lengths of adducted NSF 3 relative to those of free NSF 3 (1.531(1)–1.534(2) Å) are consistent with adduct formation .…”

“…The Lewis basicity of NSF 3 is illustrated by its reactions with the Lewis acids AsF 5 , SbF 5 , and BF 3 , which yield the Lewis acid–base adducts F 3 SNAsF 5 , , F 3 SNSbF 5 , and F 3 SNBF 3 . , Other NSF 3 adducts with main-group atom centers include [(CF 3 ) n SF 3–n NSF 3 ]­[AsF 6 ] ( n = 0–2), [F 3 S­(NSF 3 ) 2 ]­[AsF 6 ], [F 4 SNXeNSF 3 ]­[AsF 6 ], and [F 3 SNXeF]­[AsF 6 ], with the latter three adduct-cations and F 3 SNAsF 5 , having been characterized by single-crystal X-ray diffraction. The reactions of NSF 3 with Lewis acidic metal centers have also been studied and provide a series of transition metal adducts [M­(NSF 3 ) 4 ]­[AsF 6 ] 2 (M = Mn, Fe, Co, Ni, Cu, Zn), − [CpFe­(CO) 2 ­NSF 3 ]­[AsF 6 ], [M­(CO) 5 NSF 3 ]­[AsF 6 ] (M = Mn, Re), , and [Ag­(NSF 3 ) n ]­[AsF 6 ] ( n = 1, 2), which have been structurally characterized by physical methods such as IR and/or Raman spectroscopy, NMR spectroscopy, and mass spectrometry. The only transition metal complexes of NSF 3 that have been characterized by single-crystal X-ray diffraction are [M­(NSF 3 ) 4 ]­[AsF 6 ] 2 (M = Mn, Zn), [Re­(CO) 5 ­NSF 3 ]­[AsF 6 ], and [CpFe­(CO) 2 ­NSF 3 ]­[AsF 6 ] .…”

“…The reactions of NSF 3 with Lewis acidic metal centers have also been studied and provide a series of transition metal adducts [M­(NSF 3 ) 4 ]­[AsF 6 ] 2 (M = Mn, Fe, Co, Ni, Cu, Zn), − [CpFe­(CO) 2 ­NSF 3 ]­[AsF 6 ], [M­(CO) 5 NSF 3 ]­[AsF 6 ] (M = Mn, Re), , and [Ag­(NSF 3 ) n ]­[AsF 6 ] ( n = 1, 2), which have been structurally characterized by physical methods such as IR and/or Raman spectroscopy, NMR spectroscopy, and mass spectrometry. The only transition metal complexes of NSF 3 that have been characterized by single-crystal X-ray diffraction are [M­(NSF 3 ) 4 ]­[AsF 6 ] 2 (M = Mn, Zn), [Re­(CO) 5 ­NSF 3 ]­[AsF 6 ], and [CpFe­(CO) 2 ­NSF 3 ]­[AsF 6 ] . The NSF 3 ligands of these complexes are terminally N-coordinated to the metal.…”

On the Reactivity of F3S≡NXeF+: Syntheses and Structural Characterizations of [F4S═N−Xe---N≡SF3][AsF6], a Rare Example of a N−Xe−N Linkage, and [F3S(N≡SF3)2][AsF6]

“…The SF 3 + cation has been previously characterized as its AsF 6 − , ,− SbF 6 − , , PF 6 − , , BF 4 − , ,− and GeF 6 − salts. A series of mixed CF 3 /F adduct cations, [(CF 3 ) n (F) 3− n S---NSF 3 ][AsF 6 ] ( n = 0−2), has been studied by 19 F NMR spectroscopy in SO 2 solvent at temperatures below −30 °C where the cations corresponding to n = 0 or 1 are labile and weakly coordinated .…”

“…The basicity of thiazyl trifluoride, NSF 3 , has been demonstrated by its reactions with BF 3 , AsF 5 , and SbF 5 in SO 2 to form the Lewis acid-base adducts F 3 SNBF 3 , , F 3 SNAsF 5 , , and F 3 SNSbF 5 ; by the formation of transition-metal complexes such as [M(NSF 3 ) 4 (AsF 6 ) 2 ] (M = Mn, Zn), [Re(CO) 5 NSF 3 ][AsF 6 ], and [CpFe(CO) 2 NSF 3 ][AsF 6 ]; and more recently by the synthesis and structural characterization of the noble-gas-containing Lewis acid-base adduct F 3 SNXeF + …”