We investigated the effect of ionic liquid molecules (ILMs) in hybrid quantum dot-organic solar cells (HyQD-OSCs). The insertion of an ILM layer between PbS and phenyl-C61-butyric acid methyl ester (PCBM) can shift the band edge of PCBM closer to the vacuum level of PbS due to spontaneous dipole polarization. Because of this new architecture, improvements in device performance were achieved, including increases in open-circuit voltage (VOC, from 0.41 V to 0.49 V), fill factor (FF, from 0.48 to 0.59), and power conversion efficiency (PCE, from 1.62% to 2.21%), compared to reference devices under AM 1.5G illumination at 100 mW cm(-2). We observed that treatment of the PbS layer with ILMs causes a significant increase in work function from 3.58 eV to 3.93 eV. Furthermore, the ILMs layer minimizes the contact resistance between PbS and PCBM due to the improved compatibility between the two layers, confirmed as a decrease in charge transfer resistance, as measured by electrical impedance spectroscopy.
Natural rubber-epoxidized natural rubber-silica composites were prepared by the wet masterbatch technique and the traditional dry mixing method. Performances of the composites based on different preparation methods were investigated with a moving die rheometer, an electronic universal testing machine, a dynamic mechanical analyzer, a nuclear magnetic resonance crosslink density analyzer, a rubber processing analyzer (RPA), a scanning electron microscope (SEM), and a transmission electron microscope (TEM). The RPA, SEM, and TEM analyses indicated that silica has better dispersion, lower filler-filler interaction, and better filler-rubber interaction in compounds based on the wet masterbatch technique, leading to improvements in mechanical strength and the dynamic mechanical and compression properties of the composites. It also indicates that composites prepared by the wet masterbatch technique have shorter scorch time, faster curing velocity, and higher crosslink density. The composites prepared by the wet materbatch technique also have lower rolling resistance, which is an important property for their use as a green material for the tire industry.
Background: Higher tumor expression of CD44, a marker of cancer stem cells (CSCs), is associated with poor overall survival (OS) in various cancers. However, the association between CD44 and poor OS remains inconsistent in glioma. We aimed to evaluate the potential predictive role of CD44 for prognosis of glioma patients in a meta-analysis. Methods: Observational studies comparing OS of glioma patients according to the level of CD44 were identified through searching PubMed, Embase, and Cochrane’s Library databases. Meta-analyses were performed with a random- or fixed-effect model according to the heterogeneity. Subgroup analyses were performed to evaluate the influences of study characteristics. Results: Eleven retrospective cohort studies were included. Results showed that increased CD44 expression in tumor predicted poor OS in glioma patients (hazard ratio [HR]: 1.42, 95% confidence interval [CI]: 1.02–1.97, P=0.04). Subgroup analyses showed that higher tumor CD44 expression significantly predicted poor OS in patients with World Health Organization (WHO) stages II–III glioma (HR: 2.99, 95% CI: 1.53–5.89, P=0.002), but not in patients with glioblastoma (HR: 1.26, 95% CI: 0.76–2.08, P=0.47; P for subgroup difference = 0.03). Results were not statistically different between subgroups according to patient ethnicity, sample size, CD44 detection method, CD44 cutoff, HR estimation, univariate or multivariate analysis, or median follow-up durations (P-values for subgroup difference all >0.10). Conclusion: Higher tumor expression of CD44 may predict poor survival in patients with glioma, particularly in those with WHO stage II–III glioma.
A higher-order mechanical model of axially moving nanoscale beams with time-dependent velocity was developed in the framework of nonlocal stress gradient theory. Based on the correlation between effective and common nonlocal bending moments, a sixth-order partial differential equation of motion with respect to the transverse displacement was derived. Unlike some previous work which assumed the velocity of axially moving nanoscale beam to be a constant, a time-dependent axial velocity was considered for the nanoscale beams. The resonance vibration frequencies were obtained according to the governing equation of motion and corresponding boundary conditions. It was concluded a nonlocal nanoscale strengthening effect that the vibration frequencies of such axially moving nanostructure increase with stronger nonlocal effects, or a larger dimensionless nonlocal nanoscale parameter causes a higher vibration frequency. A jumping phenomenon in frequency field was observed, and the vibration frequency may decrease or increase with an increase in the axial average velocity. Critical speeds of the axially non-uniformly moving nanoscale beams were defined and determined, and the critical speed versus nonlocal nanoscale revealed step and strengthening effects. The theoretical results obtained were compared with some experimental data and good agreement was achieved. Subsequently, the steady-state and stability of such moving nanostructures including the principal parametric and combination resonances were analyzed using a multiple-scale method. Some beneficial analytical procedures and theoretical formulations at nanoscale were provided. Based on specific boundary conditions, the stability boundaries of the axially accelerating nanoscale beams were determined and the unstable regions were influenced by nonlocal nanoscale significantly.
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