With the recent interest in data storage in flexible electronics, highly reliable charge trap-type organic-based non-volatile memory (CT-ONVM) has attracted much attention. CT-ONVM should have a wide memory window, good endurance, and long-term retention characteristics, as well as mechanical flexibility. This paper proposed CT-ONVM devices consisting of band-engineered organic-inorganic hybrid films synthesized via an initiated chemical vapor deposition process. The synthesized poly(1,3,5-trimethyl-1,3,5,-trivinyl cyclotrisiloxane) and Al hybrid films are used as a tunneling dielectric layer and a blocking dielectric layer, respectively. For the charge trapping layer, different Hf, Zr, and Ti hybrids are examined, and their memory performances are systematically compared. The best combination of hybrid dielectric stacks showed a wide memory window of 6.77 V, good endurance of up to 10 4 cycles, and charge retention of up to 71% after 10 8 s even under the 2% strained condition. The CT-ONVM device using the hybrid dielectric stacks outperforms other organic-based charge trap memory devices and is even comparable in performance to conventional inorganic-based poly-silicon/oxide/nitride/oxide/silicon structures devices. The CT-ONVM using hybrid dielectrics can overcome the inherent low reliability and process complexity limitations of organic electronics and expedite the realization of wearable organic electronics.
The sound pressure generated by thermo‐acoustic (TA) loudspeakers is proportional to the frequency of the sound. This characteristic yields a low sound pressure level (SPL) in the low‐frequency region, hindering the practical application of TA loudspeakers. The limitation of low SPL is approached by using a resonating structure, in which a TA sound generator, such as multiwalled carbon nanotube sheet, is enclosed within a cavity covered by a vibrating plate. However, the cavity‐plate resonator produces an amplified SPL only around the resonating frequency, so its operating frequency bandwidth is narrow. Hence, a multiway TA loudspeaker consisting of multiple resonators that can amplify sound over a wide frequency range is designed. An accurate mechanical model is presented for predicting the resonance frequency and it shows that the behavior of resonators designed from the proposed model matches the theory well. The model enables the fine‐tuning of resonances through the application of different materials for a resonator plate and by changing the structural dimensions. A crossover network for combining multiple TA resonators is designed, and the total frequency response shows a flat frequency response with amplified SPL. These improvements open up possibilities for the use of TA loudspeakers as a practical audio device.
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