No abstract

Biomass fuel is used for cooking and heating, especially in developing countries. Combustion of biomass fuel can generate high levels of indoor air pollutants, including particulate matter (PM) and volatile organic compounds (VOCs). This study characterized PM and VOC emissions from cow dung combustion in a controlled experiment. Dung from grass-fed cows was dried and combusted using a dual-cone calorimeter. Heat fluxes of 10, 25, and 50 kW/m(2) were applied. The concentrations of PM and VOCs were determined using a dust spectrometer and gas chromatography/mass spectrometry, respectively. PM and VOC emission factors were much higher for the lower heat flux, implying a fire ignition stage. When the heat flux was 50 kW/m(2), the CO2 emission factor was highest and the PM and VOC emission factors were lowest. Particle concentrations were highest in the 0.23-0.3 μm size range at heat fluxes of 25 and 50 kW/m(2). Various toxic VOCs, including acetone, methyl ethyl ketone, benzene, and toluene, were detected at high concentrations. Although PM and VOC emission factors at 50 kW/m(2) were lower, they were high enough to cause extremely high indoor air pollution. The characteristics of PM and VOC emissions from cow dung combustion indicated potential health effects of indoor air pollution in developing countries.

This study characterized emissions of particulate matter (PM), volatile organic compounds (VOCs), heavy metals, and anions from Mongolian bituminous coals in a controlled heating experiment. Three coal samples from Alag Tolgoi (coal 1), Baganuur (coal 2), and Nalaikh (coal 3) were combusted at a constant heat flux of 50 kW/m2 using a dual-cone calorimeter. The coal samples were commonly used in ger district of Ulaanbaatar, Mongolia. PM10 emission factors were 1122.9 ± 526.2, 958.1 ± 584.0, and 472.0 ± 57.1 mg/kg for coal samples 1, 2, and 3, respectively. PM with a diameter of 0.35–0.45 µm was dominant and accounted for 41, 34, and 48% of the total PM for coal samples 1, 2, and 3, respectively. The emissions of PM and VOC from coals commonly used in Ulaanbaatar, Mongolia were significant enough to cause extremely high levels of indoor and outdoor air pollution.

Vinyl samples were burned in a controlled environment to determine the characteristics of particulate matter (PM) and volatile organic compound (VOC) emissions during the combustion process. Open burning of plastic or vinyl products poses several environmental and health risks in developed and developing countries, due to the release of high concentrations of harmful pollutants. The production of fine and ultrafine particles was significant. At a heat flux of 25 kW/m2, the production of PM of 0.35 μm in size was highest at 63.0 μg/m3. In comparison, at fluxes of 35 and 50 kW/m2, the production of PM of 0.45 μm in size was highest with values of 67.8 and 87.7 μg/m3, respectively. Benzene, acetone, and other toxic compounds were also identified in the analyses.