A series of Al-Cr-SiN hard coatings were deposited on WC-Co substrates with a negative substrate bias voltage ranging from-50 to-200 V using cathodic arc evaporation system. A Rockwell-C adhesion test demonstrated that excellent adhesion was observed at lower bias voltages of-50 V and-80 V, while further increases in bias voltage up to-200 V led to severe delamination and worsening of the overall adhesion strength. X-ray diffraction and transmission electron microscopy analysis revealed a single phase cubic B1-structure identified as an AlCrN solid solution with a nanocomposite microstructure where cubic AlCrN nanocrystals were embedded in a thin continuous amorphous SiNx matrix. Coatings exhibited a 002-texture evolution that was more pronounced at higher bias voltages (≥-120 V). Stress-induced cracks were observed inside the coatings at high bias voltages (≥-150 V), which resulted in stress relaxation and a decline in the overall residual stresses.
This research aims to develop the direct soldering of aluminum nitride (AlN) ceramics with a copper substrate using Zn–Al–Mg solder. The solder type, Zn5Al3Mg, has a close-to eutectic composition with a melting point of 359 °C. The microstructure of Zn–Al–Mg solder is composed of solid solution (Al), solid solution (Zn), an Mg2Zn11 phase and a minority MgZn2 phase. The tensile strength is from 82 to 169 MPa and depends on the magnesium content. The bond with AlN ceramics is formed due to the interaction of active Zn, Al and Mg metals with the substrate surface without forming a new transition phase. Zn and Al elements exert a substantial effect on bond formation with the Cu substrate. Magnesium does not contribute to bond formation with the Cu substrate. Two new phases, CuZn4-ε and Cu33Al17/Cu9Al4/Cu5Zn8- γ, were observed, and form the transition zone of the joint. The maximum shear strength of the AlN/Cu joint fabricated using Zn5Al3Mg solder is 47 MPa. The maximum shear strength of the Cu/Cu joint fabricated using the same solder is 93 MPa.
The paper concerns with welding of copper to stainless steel. Technically pure Cu and AISI 304 austenitic stainless steel with the thickness of 2.0 mm were suggested as experimental metals. TruDisk 8002 laser with the wavelength of 1.03 μm and a maximum power of 8.0 kW was used for production of dissimilar metal welds. Laser power from the range of 2.3 to 2.9 kW and welding speed from 35 to 50 mm/s were used for welding dissimilar metals. Focal position was direct on the surface of welded metals. Helium with flow rate of 17 l/min was used for shielding of molten weld metal. Light microscopy, EDX microanalysis and micro hardness measurements across copper - fusion zone - stainless steel interface were performed in order to study the properties of the weld joints.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.