This paper reports the results of photocapacitance measurements applied to the metal‐
SiO2‐normalSi
structure. Photocapacitance measurements under a constant capacitance condition determine the spatial distribution of deep levels existing at
normalSi/SiO2
interface regions. The photocapacitance method revealed deep levels distributed in a spectral region of 0.4–1.05 eV optically, and an optical level located 1.05 eV below the conduction band in the n‐
normalSi/SiO2
interface region. With respect to p‐
normalSi/SiO2
, deep levels distributed at 0.4–0.85 eV and 0.85 eV, 1.05 eV levels above the valence band, were observed. Differences of interface level densities are shown as a function of Si conduction type and different preparations of oxide layers. Comparisons with the results of capacitance‐voltage measurements are also discussed. © 1999 The Electrochemical Society. All rights reserved.